Orthogonal Expression of an Artificial Metalloenzyme for Abiotic Catalysis
نویسندگان
چکیده
منابع مشابه
Cross‐Regulation of an Artificial Metalloenzyme
Cross-regulation of complex biochemical reaction networks is an essential feature of living systems. In a biomimetic spirit, we report on our efforts to program the temporal activation of an artificial metalloenzyme via cross-regulation by a natural enzyme. In the presence of urea, urease slowly releases ammonia that reversibly inhibits an artificial transfer hydrogenase. Addition of an acid, w...
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Although chemical and enzymatic catalysts have been combined, reactions in which an organometallic catalyst and a metalloenzyme work cooperatively to create products, which cannot be generated with either catalyst alone or in comparable yields by sequential reactions of the two catalysts, have not been reported. Such reactions are challenging to achieve, in part because the milieu in which thes...
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Co-immobilization of an Enzyme and a Metal into the Compartments of Mesoporous Silica for Cooperative Tandem Catalysis: An Artificial Metalloenzyme**
As a result of natural evolution for millions of years, enzymes constitute the state of the art in catalysis, with their ability to efficiently catalyze a wide range of important chemical reactions under mild conditions. Among the enzymes, metalloenzymes stand out as the most impressive examples, and they are involved in several important processes in nature, such as water oxidation, photosynth...
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in the area of automotive engineering there is a tendency to more electrification of power train. in this work control of an induction machine for the application of electric vehicle is investigated. through the changing operating point of the machine, adapting the rotor magnetization current seems to be useful to increase the machines efficiency. in the literature there are many approaches wh...
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ژورنال
عنوان ژورنال: ChemBioChem
سال: 2017
ISSN: 1439-4227,1439-7633
DOI: 10.1002/cbic.201700397